https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 Production of p-cymene by alkylation of toluene with propan-2-ol https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:50987 Wed 16 Aug 2023 13:22:57 AEST ]]> Rate constants for hydrogen abstraction reactions by the hydroperoxyl radical from methanol, ethenol, acetaldehyde, toluene and phenol https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:9026 Wed 11 Apr 2018 13:34:25 AEST ]]> Identifying the best materials for the removal of airborne toluene based on performance metrics - a critical review https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:37262 -1. Of the advanced materials, the metal organic framework, MIL-101 has an acceptable value of 985 L g-1. Likewise, judgement based on a figure of merit basis (e.g., regeneration, reusability, breakthrough volume, and cost) confirms the apparent superiority of activated carbon for the removal of aromatic hydrocarbons like toluene over all sorbent materials evaluated on parallel basis.]]> Tue 15 Sep 2020 12:16:30 AEST ]]> Natural zeolite supported Ni catalysts for hydrodeoxygenation of anisole https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:43843 Tue 04 Oct 2022 11:46:23 AEDT ]]> Rate constants for hydrogen abstraction reactions by the hydroperoxyl radical from methanol, ethenol, acetaldehyde, toluene, and phenol https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:17541 2). In this study, we calculate energy profiles for the sequence: reactant + HO2 → [complex of reactants] → transition state → [complex of products] → product + H2O2 for methanol, ethenol (i.e., C2H3OH), acetaldehyde, toluene, and phenol. Rate constants are provided in the simple Arrhenius form. Reasonable agreement was obtained with the limited literature data available for acetaldehyde and toluene. Addition of HO2 to the various distinct sites in phenol is investigated. Direct abstraction of the hydroxyl H was found to dominate over HO2 addition to the ring. The results presented herein should be useful in modeling the lower temperature oxidation of the five compounds considered, especially at low temperature where the HO2 is expected to exist at reactive levels.]]> Sat 24 Mar 2018 08:03:57 AEDT ]]> Novel methodologies for automatically and simultaneously determining BTEX components using FTIR spectra https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:26475 -1), to simultaneously determinate multiple petroleum hydrocarbons (PHs) in real mixture samples. This system includes: an object oriented baseline correction; Band decomposition (curve fitting) method with mathematical optimization; and Artificial Neural Network (ANN) for determination, which is suitable for the characteristics of this IR regions, where the spectra are normally with low signal to noise ratio and high density of peaks. BTEX components are potentially lethal carcinogens and contained in many petroleum products. As a case study, six BTEX components were determinate automatically and simultaneously in mixture vapor samples. The robustness of the BTEX determination was validated using real petroleum samples, and the prediction results were compared with gas chromatography-mass spectrometry (GC-MS).]]> Sat 24 Mar 2018 07:27:14 AEDT ]]> Optimization of non-thermal plasma efficiency in the simultaneous elimination of benzene, toluene, ethyl-benzene, and xylene from polluted airstreams using response surface methodology https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:35378 adj) and the F-test. The results revealed that the R² proportion was greater than 0.96 for BTEX removal efficiency. The statistical analysis demonstrated that the BTEX removal efficiency was significantly correlated with the temperature, BTEX concentration, voltage, and flow rate. Voltage was the most influential variable affecting the dependent variable as it exerted a significant effect (p < 0.0001) on the response variable. According to the achieved results, NTP can be applied as a progressive, cost-effective, and practical process for treatment of airstreams polluted with BTEX in conditions of low residence time and high concentrations of pollutants.]]> Mon 22 Jul 2019 13:12:18 AEST ]]> Improved extraction of saturated fatty acids but not Omega-3 fatty acids from sheep red blood cells using a one-step extraction procedure https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:27736 Fri 26 May 2017 11:27:53 AEST ]]>